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9th Class Chemistry · Punjab Board · Complete learning guide

Chapter 1States of Matter and Phase Changes

Every topic, every MCQ and every exercise question, explained step by step in simple language. Written for the Punjab Board new-syllabus Chemistry book, English medium.

On their own page:Chapter 1 MCQsChapter 1 Short QuestionsChapter 1 Long Questions

  1. Read Part 1 slowly. Do the worked examples yourself on paper, then compare.
  2. Try each MCQ before opening its answer, then read why the wrong options are wrong.
  3. Learn the short answers in your own words, then write the long answers from memory.
  4. Finish with the self-test in Part 6. A wrong answer tells you which topic to read again.
Part 1of 6

Learn the Chapter

Read this first. Everything in the exercises comes from these topics.

  1. 1What is chemistry?
  2. 2The states of matter
  3. 3Intermediate and exotic states
  4. 4Elements, compounds and mixtures
  5. 5Elements, compounds and mixtures compared
  6. 6Allotropic forms
  7. 7Solutions, colloids and suspensions
  8. 8Unsaturated and saturated solutions
  9. 9Effect of temperature on solubility
Topic 1

What is chemistry?

Definition
Chemistry

Chemistry is the branch of science which deals with the properties, composition and the structure of substances. It also deals with the physical and chemical changes in matter and the laws or principles which govern these changes.

Composition means the percentages of elements and compounds in a sample. Structure means the arrangement of atoms in it. Changes may happen with the absorption or release of energy.

BranchWhat it studies
Physical chemistryHow substances behave at atomic and molecular level; energy and rates of reactions
Inorganic chemistryElements and compounds containing little or no carbon: metals, salts, acids, bases
Organic chemistryCarbon compounds (hydrocarbons and their derivatives), except simple salts like carbonates
Environmental chemistryChemicals in air, soil and water; causes and cures of pollution
Analytical chemistrySeparating, identifying and measuring the components of a material
BiochemistryChemical processes in living organisms: proteins, carbohydrates, lipids, nucleic acids
Nuclear chemistryReactions in the nucleus; radioactivity
Polymer chemistryLarge chain molecules (polymers), natural and synthetic
GeochemistryChemical composition of the Earth, its rocks and minerals
Medicinal chemistryDesign and synthesis of drugs and how the body handles them
AstrochemistryAtoms, molecules and ions in space and their reactions
Remember

Chemistry is divided into branches because it is a vast subject: each branch lets scientists focus on one area and make faster progress.

Topic 2

The states of matter

Definition
Matter

Anything other than energy which carries weight and occupies volume is called matter. Energy is non-material in nature.

Definition
State of matter

A state of matter is one of the many distinct forms in which matter can exist. We observe four states in everyday life: solid, liquid, gas and plasma.

Solidfixed positions, vibrateLiquidclose, slide past each otherGasfar apart, move freelyheating: the molecules move faster and further apart
Particles in a solid, a liquid and a gas.
PropertySolidLiquidGas
Particlesclosely packed, fixed positionsclose, moving at randomvery far apart, no order
Intermolecular forcesvery strongsignificantvery weak
Densityvery highhighvery low
Compressibilityalmost incompressiblehardly compressibleeasily compressible
Fluiditydoes not flow (rigid)flowsflows freely
Shape and volumedefinite shape and volumedefinite volume, takes the container's shapefills any container
Definition
Plasma

Plasma is composed of particles with very high kinetic energy. It can be considered as a partially ionised gas containing electrons, ions, photons, etc. It exists in fluorescent tubes, lightning and welding arcs.

Remember

Most of the matter in the universe (in stars) is plasma, though it is rare on Earth.

Topic 3

Intermediate and exotic states

Matter can also exist in states at the border between two principal states.

StateBetweenKey pointUse
Supercritical fluidliquid and gashighly compressed; shows properties of both liquids and gasesreactions that fail in ordinary solvents can be run in supercritical CO₂; decaffeinating coffee
Liquid crystalliquid and crystalline solidflows like a liquid but its molecules keep some orderdisplays of monitors, clocks, watches, navigation systems
Graphenea two-dimensional crystalone layer of carbon atoms in hexagons; tough, flexible, lightelectronics, sensors, batteries
Definition
Exotic states

States of matter that are not commonly encountered are called exotic states of matter, e.g. dark matter, Bose-Einstein condensate, nuclear matter and quantum spin liquid.

Topic 4

Elements, compounds and mixtures

Elementone kind of atomCompoundatoms bonded in a fixed ratioMixturesubstances mixed, not bonded
Particles in an element, a compound and a mixture.
Definition
Element

Element is the simplest form of matter. It is a pure substance containing the same kind of atoms. It cannot be broken down into simpler substances by ordinary chemical reactions.

Definition
Compound

Compound is also a pure substance. It is made up of two or more different elements chemically combined in a fixed ratio. Examples: water, ammonia, methane, carbon dioxide.

Definition
Mixture

A mixture is formed when more than one type of elements or compounds are mixed together in any ratio. Examples: air, soil, milk, tap water.

Homogeneous mixtureHeterogeneous mixture
Same composition throughoutComposition differs from part to part
Salt solution, air, vinegarRock, soil, concrete, sand in water

Most elements are solids; only a few are liquids (mercury, bromine) or gases (hydrogen, oxygen, nitrogen, chlorine, the noble gases). Elements may be metals, non-metals, metalloids or noble gases.

Interesting

Technetium was the first element to be made artificially in a laboratory.

Topic 5

Elements, compounds and mixtures compared

ElementCompoundMixture
Simplest form of matter; one kind of atomPure substance of two or more elements chemically combinedImpure: two or more substances mixed in any ratio
Cannot be broken down by ordinary chemical reactionsCan be broken into its elements by a chemical reaction (ammonia → nitrogen + hydrogen)Separated by physical methods
Represented by a symbol: Na, CaFixed ratio by mass: H : O = 1 : 8 in waterNo fixed ratio
Gases form molecules N₂, O₂, Cl₂; noble gases are monatomic (He, Ar)Properties differ from those of its elementsEach component keeps its own properties
—Exists as molecules (HCl, NH₃, H₂O) or networks (NaCl, SiO₂)Homogeneous or heterogeneous
Topic 6

Allotropic forms

Definition
Allotropy

Elements may exist in more than one structural form which can exhibit quite different physical and chemical properties. These forms are called allotropic forms and the phenomenon is called allotropy.

Diamondeach C bonded to 4 othersGraphitelayers of hexagonsBuckminster fullereneC₆₀ cage: 12 pentagons, 20 hexagonsweak forces between layers (dashed)
Diamond, graphite and buckminster fullerene: three allotropes of carbon.
ElementAllotropes
Oxygenoxygen O₂ and ozone O₃
Carbondiamond, graphite, buckminster fullerene C₆₀ (coal is amorphous carbon)
Sulphurrhombic and monoclinic (rhombic is more stable)
DiamondGraphiteFullerene C₆₀
Giant 3-D structure: each C bonded to four othersFlat layers of hexagonal ringsHollow cage of pentagons and hexagons
Hardest natural substanceSoft, slippery layersSoft, low melting point
Does not conduct electricityConducts electricityDoes not conduct; soluble in organic solvents
Topic 7

Solutions, colloids and suspensions

SolutionColloidal solutionSuspensionparticles: cannot be seenparticles: cannot be seenparticles: can be seenon standing: do not settleon standing: do not settleon standing: settle downfilter paper: pass throughfilter paper: pass throughfilter paper: left as residue
A true solution, a colloid and a suspension in beakers, and what happens on standing and on filtering.
Definition
True solution

A solution is such a mixture in which solute particles are completely homogenised in the solvent, e.g. sodium chloride or copper sulphate in water. The particles cannot be seen and pass through filter paper leaving no residue.

Definition
Colloidal solution

A mixture whose solute particles are a little bigger than those of a true solution but not big enough to be seen with the naked eye. They do not settle down and pass through filter paper. Examples: starch solution, white of an egg.

Definition
Suspension

A suspension is a mixture in which solute particles do not dissolve in the solvent. The particles can be seen, settle down on standing and are collected as a residue on filter paper. Example: chalk in water.

PropertyTrue solutionColloidSuspension
Particle sizesmallestmediumlargest
Visible to the eye?nonoyes
Settle on standing?nonoyes
Pass through filter paper?yesyesno (residue)
Examplesalt watermilkchalk in water
Topic 8

Unsaturated and saturated solutions

Definition
Unsaturated solution

A solution which can dissolve more amount of a solute at a particular temperature is called an unsaturated solution.

Definition
Saturated solution

A solution in which the maximum amount of the solute has been dissolved in a particular amount of a solvent at a particular temperature is called a saturated solution.

Activity
  1. Put about 100 g of water in a beaker and stir in 5 g of sugar: it dissolves (unsaturated).
  2. Add 5 g more: it still dissolves.
  3. Keep adding sugar: dissolving gets harder.
  4. At last no more dissolves; extra sugar settles at the bottom: the solution is saturated at that temperature.
255075100125150175200225250020406080100ABCSupersaturatedC: 100 g at 40 °C (above the curve)UnsaturatedA: 30 g at 40 °C (below)Saturatedon the curve · B: 64 g at 40 °CTemperature (°C)g of KNO₃ per 100 g water
On a solubility curve: below the line unsaturated, on it saturated, above it supersaturated.

Different solutes have different solubilities: at 20 °C, 100 g of water dissolves about 36 g of sodium chloride but about 204 g of table sugar. More water molecules can surround one large sugar molecule, so sugar dissolves in larger amounts.

Topic 9

Effect of temperature on solubility

Definition
Solubility

The solubility of a solute is the amount of solute which can dissolve in 100 g of a solvent at a particular temperature.

01020304050607080901001101201301401500102030405060708090100KINaNO₃KNO₃NH₄ClHClNH₃KClNaClKClO₃SO₂Temperature (°C)grams of solute per 100 g H₂Osolid lines: salts · dashed lines: gases
Solubility curves: KNO₃ rises steeply, KCl and KClO₃ rise, NaCl hardly changes, SO₂ (a gas) falls.
Effect of a rise in temperatureExamples
Solubility increases (most solids)KNO₃, AgNO₃, KCl, KClO₃, CuSO₄, NaNO₃, sugar
Hardly changesNaCl
Solubility decreasesLi₂CO₃, CaCrO₄, Ca(OH)₂, and all gases (CO₂, SO₂, O₂)
Uses of changing solubility
  • Purifying solids by crystallisation: a solid that is much more soluble when hot is dissolved in hot water and crystallises out pure on cooling.
  • Soda water: CO₂ is more soluble in cold water, so soda bottles are kept in the refrigerator.
Remember

Solubility usually increases with temperature, but this is not a general rule: gases and a few solids become less soluble.

Part 2of 6

MCQs Fully Solved

Try each one first: tap an option to check it, then read the reasoning and why the others are wrong.

Only the mcqs on one page →
A note about the questions

The wording follows published solved exercises and every answer was re-checked by hand, so the wording or the order of options may differ slightly from your print.

Answered 0 of 24 · Correct 0

Set A: Textbook exercise 10 MCQs

The multiple-choice questions at the end of Chapter 1 in your book, in the book's option order.

Q1.1States of Matter

Matter is present in neon signs in the state of:

Q1.2Branches of Chemistry

Hazardous effects of shopping bags are studied in:

Q1.3Branches of Chemistry

The man-made polymer is:

Q1.4Allotropy

The crystals of which substance have a rhombic shape?

Q1.5Solutions, Colloids and Suspensions

Which liquid among the following is a colloidal solution?

Q1.6Elements, Compounds and Mixtures

Which of the following is a heterogeneous mixture?

Q1.7States of Matter

A state of matter whose properties are between those of liquids and crystalline solids is:

Q1.8Solutions, Colloids and Suspensions

When tiny visible particles of a substance are dispersed through a medium, the mixture is named as:

Q1.9Solubility

A solution of KClO₃ has a solubility of about 13.2 g per 100 cm³ at 40 °C. How will its solubility be affected if you decrease the temperature?

Q1.10Branches of Chemistry

You are studying the rate of hydrolysis of starch under different conditions of temperature. In which branch of chemistry will this topic fall?

Set B: More MCQs from this chapter 14 MCQs

Extra questions on the same ideas, of the kind set in board papers and class tests.

QB1Branches of Chemistry

The branch of chemistry that deals with reactions in the nucleus of an atom is:

QB2Branches of Chemistry

The design and synthesis of drugs is the work of:

QB3States of Matter

Which state of matter is the most easily compressed?

QB4States of Matter

The only state of matter that does not need a container to keep its shape is:

QB5States of Matter

Bose-Einstein condensate and dark matter are examples of:

QB6States of Matter

Graphene is:

QB7Elements, Compounds and Mixtures

In water, hydrogen and oxygen are combined in a fixed ratio by mass of:

QB8Elements, Compounds and Mixtures

The components of a mixture can be separated by:

QB9Allotropy

Ozone (O₃) and oxygen (O₂) are:

QB10Allotropy

Buckminster fullerene has the formula:

QB11Solutions, Colloids and Suspensions

On filtration, the particles of which mixture are left behind on the filter paper?

QB12Solubility

At 20 °C, the mass of NaCl that dissolves in 100 g of water to give a saturated solution is about:

QB13Solubility

Soda water bottles are stored in a refrigerator because:

QB14Solubility

A solution that can still dissolve more solute at a given temperature is:

Part 3of 6

Short Questions

Exam-ready answers. Learn the meaning, then write them in your own words.

Only the short questions on one page →

Set A: Textbook exercise short questions 8 questions

The short questions at the end of the chapter in your book.

Short Q 1.1

Why is there a need to divide chemistry into many branches? Give three reasons.

Answer

To understand the widely spread complex subject of chemistry and to concentrate on its specific aspects, chemistry is divided into many distinct branches. These branches have distinct areas of study for the scientists to focus on and to achieve breakthroughs and advancements.

  1. Chemistry is too vast and complex for one person to master all of it.
  2. Each branch lets scientists focus on one area and go deep into it, which leads to breakthroughs and advancements.
  3. Each branch has its own methods and applications (medicine, industry, environment), which makes study, research and careers easier to organise.
Short Q 1.2

Reactions may take place due to electrons outside the nucleus or inside the nucleus. Which branches of chemistry cover these two types of reactions?

Answer

Reactions of the electrons outside the nucleus are ordinary chemical reactions; they are studied in physical, inorganic and organic chemistry (and the other branches that deal with chemical changes).

Nuclear chemistry deals with the reactions taking place in the nucleus of an atom. It deals with radioactivity, nuclear processes and transformation in the nuclei of atoms.

Short Q 1.3

What types of problems are solved in analytical chemistry?

Answer

Analytical chemistry deals with the analysis of different substances. It involves separation, identification and determination of the concentration of the components present in material things, nowadays with modern and sophisticated instruments.

  • What substances does a sample contain? (identification)
  • How much of each is present? (concentration)
  • How can a mixture be separated into its components?
  • Examples: testing the purity of medicines and food, checking pollutants in water, forensic tests.
Short Q 1.4

Both graphite and graphene have hexagonal layered structures. What is the difference?

Answer

Graphite has a layered structure of hexagonal rings of carbon: many layers stacked on top of each other and held by weak forces.

Graphene is an example of a two-dimensional crystal, a single layer of carbon atoms arranged in a hexagonal pattern. So graphene is just one layer of graphite.

Short Q 1.5

Why are supercritical fluids important?

Answer

Supercritical fluids are highly compressed states which show both properties of gases and liquids. Chemical reactions which may not be carried out in conventional solvents may possibly be carried out in supercritical carbon dioxide.

Supercritical CO₂ is non-toxic and leaves no residue; it is used, for example, to remove caffeine from coffee.

Short Q 1.6

In which state does matter exist in the Sun?

Answer

In the plasma state. Plasma is regarded as the fourth state of matter; most of the matter present in the rest of the universe, including the Sun and stars, exists in this state. The Sun's very high temperature ionises its gases into electrons and positive ions.

Short Q 1.7

What is the importance of graphene?

Answer

Graphene is a two-dimensional crystal, a single layer of carbon atoms arranged in a hexagonal pattern. It is a tough, flexible and light material with a high resistance to breaking.

It also conducts electricity and heat very well, so it is used or being developed for fast electronics, touch screens, sensors, batteries and strong lightweight materials.

Short Q 1.8

Which form of matter do most of the material things in this world belong to?

Answer

Solids. Elements exist in all three forms, solid, liquid and gas, but most of the elements found in this world exist in solid form; liquid and gaseous elements are very few. (In the rest of the universe most matter is plasma.)

Set B: More short questions 55 questions

The book's in-text exercises first, then short questions on every topic of the chapter (SLO-based), as asked in board papers.

Practice exercise questions (in text)

SQ 1.1
A lunar mission has recently brought samples from the Moon. Point out the branch of chemistry each experiment is related to: (1) determining its composition, (2) studying the physical properties of the materials it contains, (3) carrying out chemical reactions with usual inorganic reagents.
Answer
ExperimentBranch of chemistry
1. Determining its compositionAnalytical chemistry
2. Studying the physical properties of its materialsPhysical chemistry
3. Chemical reactions with usual inorganic reagentsInorganic chemistry
SQ 1.2
Which elements are found in the pure state on Earth?
Answer

Elements that are unreactive occur uncombined (native): gold, platinum and silver (sometimes copper) as metals; carbon as diamond and graphite; sulphur near volcanoes; and the gases nitrogen, oxygen and the noble gases in air.

SQ 1.3
Which elements are present in very small amounts on Earth?
Answer

Rare elements such as astatine and francium (radioactive; only a few grams exist in the whole crust at any time); precious elements such as gold, platinum and iridium; and the noble gases xenon and krypton in air. Technetium and promethium hardly occur naturally at all.

SQ 1.4
How can the variation of solubility at different temperatures be useful for us?
Answer

The increase in the solubility of solids in liquids with increase in temperature may be used to purify them: pure solids commonly appear as beautifully shaped crystals. Generally the solubility of gases decreases with increase in temperature, so soda water bottles are stored in the refrigerator to keep carbon dioxide dissolved for a longer time.

  • Crystallisation: KNO₃ dissolved in hot water gives pure crystals on cooling.
  • More sugar dissolves in hot tea than in cold.
  • Cold drinks keep their fizz longer.

Chemistry and its branches

SQ 1.5
Define chemistry.
Answer

Chemistry is the branch of science which deals with the properties, composition and the structure of substances. It also deals with the physical and chemical changes in matter and the laws or principles which govern these changes.

SQ 1.6
What is meant by the composition and the structure of matter?
Answer

Determination of composition represents finding out the percentages of elements and compounds in a sample of matter. Structure of matter means the arrangement of atoms in matter. Both physical and chemical changes may be brought about by absorption or evolution of energy.

SQ 1.7
Define physical chemistry.
Answer

This branch investigates how substances behave at atomic and molecular levels. It explains how fundamental physical laws cause atoms and molecules to show specific characteristics. Physical chemistry is also used to predict and change the rates of reactions and thus optimise the conditions to carry out reactions on an industrial scale.

SQ 1.8
Define inorganic chemistry. Give uses of inorganic compounds.
Answer

It is the study of the synthesis, composition, properties and structure of elements and compounds that contain little or no carbon. An inorganic substance can be composed of metals, non-metals or a mixture of these, salts, acids and bases. Inorganic compounds are used as fertilisers, medicines, catalysts, pigments, coatings and much more.

SQ 1.9
Define organic chemistry.
Answer

It is the branch of chemistry that deals with the carbon compounds (hydrocarbons and their derivatives) other than its simple salts like carbonates, bicarbonates, oxides and carbides. In this branch we study the structure, formation, properties, composition and reactions of carbon-containing compounds. Organic compounds are found in all forms of life and are essential for life.

SQ 1.10
What is environmental chemistry?
Answer

It is the scientific study of the chemical and biochemical phenomena that occur in this planet. We study the sources, reactions, effects and fates of chemical species in the air, soil and water environments. It helps in understanding the causes, effects and solutions of different types of pollution.

SQ 1.11
What is analytical chemistry?
Answer

This branch of chemistry deals with the analysis of different substances. It involves separation, identification and determination of the concentration of the components present in material things, using modern and sophisticated instruments.

SQ 1.12
What is biochemistry?
Answer

It is the branch of chemistry in which we understand life through chemical processes. It is the study of chemical substances and vital processes occurring in living organisms, and gives insight into the structure and function of proteins, carbohydrates, lipids and nucleic acids.

SQ 1.13
What is nuclear chemistry? Where is it applied?
Answer

Nuclear chemistry deals with the reactions taking place in the nucleus of an atom. It deals with radioactivity, nuclear processes and transformation in the nuclei of atoms. It has many applications in agriculture, medicine, industry and research.

SQ 1.14
What is polymer chemistry? Give examples of natural polymers.
Answer

Polymers are large molecules made by linking together a series of building blocks. Polymer chemistry focuses on the properties, structure and synthesis of polymers and macromolecules. Many materials in living organisms, including proteins, cellulose and nucleic acids, are naturally occurring polymers.

SQ 1.15
What is geochemistry?
Answer

The study of the chemical composition of the Earth and its sources and minerals is called geochemistry. Apart from its use in mineral exploration, geochemical mapping today has applications in environmental monitoring, forestry and medical research.

SQ 1.16
What is medicinal chemistry?
Answer

In this branch of chemistry, the chemist tries to design and synthesise medicines or drugs which are beneficial for mankind. It includes the discovery, delivery, absorption and metabolism of drugs in the human body.

SQ 1.17
What is astrochemistry?
Answer

It is the study of molecules and ions occurring in space and interstellar space. In this discipline we study the abundance and reactions of atoms, molecules and ions in the universe and the interaction of these species with radiation.

SQ 1.18
What is a geothermal heat pump?
Answer

A geothermal heat pump uses a pump to transfer underground water into buildings during the winter to heat them and in the summer to cool them.

States of matter

SQ 1.19
Define matter. Is energy matter?
Answer

This world is made up of matter and energy. Energy is non-material in nature. Anything other than energy which carries weight and occupies volume is called matter.

SQ 1.20
What is a state of matter? Name the states of matter.
Answer

A state of matter is one of the many distinct forms in which matter can exist. We observe four states of matter in everyday life: solid, liquid, gas and plasma. Apart from these, there are more states of matter which we do not see in our everyday life.

SQ 1.21
Why are the three primary states of matter different from each other?
Answer

The solid, liquid and gaseous states are different from each other due to the different strength of intermolecular forces, the arrangement of particles and the distance between the particles.

SQ 1.22
Why are gases easily compressible and have low densities?
Answer

In gases, molecules are very widely apart with no order whatsoever and very weak intermolecular forces. All these features make gases easily compressible. Their densities are obviously very low.

SQ 1.23
Why are liquids not easily compressible?
Answer

Liquids have molecules which are closely attached but moving randomly, and there exist significant intermolecular forces between their molecules. Liquids are therefore not easily compressible and their densities are higher than those of gases.

SQ 1.24
Why are solids rigid and almost incompressible?
Answer

Particles in solids are closely packed and have very strong interatomic or intermolecular attractions. The particles remain fixed at their positions where they can oscillate about their mean positions. Solids are therefore relatively incompressible and rigid. In crystalline solids, particles are perfectly arranged and strongly bonded, which makes them almost incompressible.

SQ 1.25
Why do solids not need a container to be stored?
Answer

Solids have a definite shape and a fixed volume. They are the only state of matter which does not need any container to be stored.

SQ 1.26
What is plasma? Where is it found?
Answer

Plasma is not a generally seen form of matter. It is composed of particles with very high kinetic energy. It exists in fluorescent tubes, lightning and welding arcs. Plasma can be considered as a partially ionised gas containing electrons, ions, photons, etc.

SQ 1.27
What are intermediate states of matter? Give examples.
Answer

Matter also exists in intermediate states, where liquid meets gas and liquid meets solid, for example supercritical fluids, liquid crystals and graphene.

SQ 1.28
What are supercritical fluids?
Answer

Supercritical fluids are highly compressed states which show both properties of gases and liquids. Chemical reactions which may not be carried out in conventional solvents may possibly be carried out in supercritical carbon dioxide.

SQ 1.29
What are liquid crystals? Give their uses.
Answer

Liquid crystal is a state of matter whose properties are between those of conventional liquids and those of crystalline solids. Liquid crystals are used in display devices including computer monitors, clocks, watches and navigation systems.

SQ 1.30
What is graphene?
Answer

Graphene is an example of a two-dimensional crystal, a single layer of carbon atoms arranged in a hexagonal pattern. Graphene is a tough, flexible and light material with a high resistance.

SQ 1.31
What are exotic states of matter?
Answer

States of matter that are not commonly encountered are called exotic states of matter. Examples are dark matter, Bose-Einstein condensate, nuclear matter and quantum spin liquid.

Elements, compounds and mixtures

SQ 1.32
Define an element. Give examples.
Answer

Element is the simplest form of matter. It is a pure substance containing the same kind of atoms. It cannot be broken down into simpler substances by ordinary chemical reactions. Elements may be a metal, a non-metal, a metalloid or a noble gas, and can exist as atoms, molecules, ions and isotopes.

Examples: sodium, potassium, magnesium, calcium, carbon, nitrogen, oxygen, chlorine, copper, gold, mercury and bromine.

SQ 1.33
In which physical state are most elements found?
Answer

Elements exist in all three forms, solid, liquid and gas, but most of the elements found in this world exist in solid form. Liquid and gaseous elements are very few in number compared with solids.

SQ 1.34
Define a compound. Give examples.
Answer

Compound is also a pure substance. It is made up of two or more different elements chemically combined in a fixed ratio. When elements come together they react and form chemical bonds that are not easy to break. Compounds may be molecular, ionic, intermetallic or coordination complexes, and inorganic or organic.

Examples: water, ammonia, methane, carbon dioxide, sodium carbonate, potassium chloride, starch and proteins.

SQ 1.35
Define a mixture. Differentiate between homogeneous and heterogeneous mixtures.
Answer

A mixture is formed when more than one type of elements or compounds are mixed together in any ratio. Air, soil, milk and tap water are everyday examples of mixtures.

Homogeneous mixtureHeterogeneous mixture
Concentration is uniform throughout.Concentration of its constituents is different in different parts.
A solution of salt in water.A sample of rock (granite, mica, limestone).
SQ 1.36
In what ratio by weight are hydrogen and oxygen present in water?
Answer

In a compound the atoms combine in a fixed ratio by weight. In water (H₂O), hydrogen and oxygen are present in a fixed ratio of 1 : 8 by weight.

SQ 1.37
How can a compound be broken into its elements? Give an example.
Answer

It is possible to break a compound into its constituent elements by a chemical reaction. For example, ammonia can be converted back to nitrogen and hydrogen by a suitable chemical reaction.

SQ 1.38
How are the components of a mixture separated?
Answer

The components of a mixture are not chemically bound together and they can be separated by physical methods, such as filtration, evaporation, distillation and crystallisation. Each component retains its identity and specific properties.

SQ 1.39
In what form do gaseous elements and noble gases exist?
Answer

Gaseous elements exist in the form of independent molecules, for example nitrogen (N₂), oxygen (O₂) and chlorine (Cl₂). Noble gases, however, exist as monatomic molecules, for example helium (He) and argon (Ar).

SQ 1.40
Which was the first element created in the laboratory?
Answer

Many elements are found in nature but some are artificial. Technetium was the first element created by scientists in the laboratory.

Allotropy

SQ 1.41
Define allotropy. Give examples.
Answer

Elements may exist in more than one structural form which can exhibit quite different physical and chemical properties. These forms are called allotropic forms and the phenomenon is called allotropy.

Oxygen exists as oxygen (O₂) and ozone (O₃); carbon as diamond, graphite and buckminster fullerene; sulphur as rhombic and monoclinic.

SQ 1.42
Name the allotropic forms of sulphur. Which is more stable?
Answer

Element sulphur exists in two crystalline allotropic forms, rhombic and monoclinic; the former (rhombic) is more stable than the latter.

SQ 1.43
Describe the structure and properties of buckminster fullerene.
Answer

Buckminster fullerene (C₆₀) consists of spheres made of atoms arranged in pentagons and hexagons. Fullerenes are stable at high temperatures and high pressures. Being covalent, they are soluble in organic solvents. The molecule is not charged, has no boundaries and has no unpaired electrons; it has a cage-like structure. C₆₀ has a low melting point, is soft and cannot conduct electricity.

SQ 1.44
How does diamond differ from graphite in structure?
Answer

Diamond has a giant macromolecular structure in which every carbon is bonded to four others, whereas graphite has a layered structure of hexagonal rings of carbon.

Solutions, colloids and suspensions

SQ 1.45
Define a true solution. Give examples.
Answer

A solution is such a mixture in which solute particles are completely homogenised in the solvent, e.g. dissolution of sodium chloride or copper sulphate in water. The solute particles cannot be seen by the naked eye. If the solution is filtered, these particles pass through the pores of filter paper leaving no residue. Such a solution is called a true solution.

SQ 1.46
Define a suspension. Give an example.
Answer

A suspension is a mixture in which solute particles do not dissolve in the solvent. We can actually see these particles. If a suspension is kept for some time, these particles settle down, and on filtering they cannot pass through the pores of filter paper and are collected as a residue. A mixture of chalk in water is an example.

SQ 1.47
Define a colloidal solution. Give examples.
Answer

In a colloidal solution the solute particles do not homogenise with the solvent. These particles are a little bigger than the solute particles of a true solution but not big enough to be seen with the naked eye. If kept for some time they do not settle down, and on filtration they pass through filter paper. Starch solution and white of an egg are common examples.

SQ 1.48
How are mixtures related to our everyday lives?
Answer

Mixtures are closely related to our everyday lives. The air we breathe, the foods we consume, the fluids in our body and solids like steel are all either homogeneous or heterogeneous mixtures.

Saturated solutions and solubility

SQ 1.49
Define an unsaturated solution and a saturated solution.
Answer

A solution which can dissolve more amount of a solute at a particular temperature is called an unsaturated solution.

A solution in which the maximum amount of the solute has been dissolved in a particular amount of a solvent at a particular temperature is called a saturated solution.

SQ 1.50
How will you prepare a saturated solution of sugar?
Answer

Take about 100 g of water in a beaker, add 5 g of table sugar and stir; it dissolves. Add another 5 g; this also dissolves (unsaturated solution). Continue adding sugar: dissolution becomes more difficult, and a stage comes when no more sugar will dissolve and any more settles at the bottom. The solution is now saturated at that temperature.

SQ 1.51
Define solubility.
Answer

The solubility of a solute is the amount of solute which can dissolve in 100 g of a solvent at a particular temperature.

SQ 1.52
Why is table sugar more soluble in water than sodium chloride?
Answer

At 20 °C, 36 g of sodium chloride dissolves in 100 g of water but 203.9 g of table sugar dissolves. This is because sugar molecules are larger than salt ions, so more water molecules can surround a single sugar molecule, causing it to dissolve in larger amounts.

SQ 1.53
How does temperature affect solubility? Give examples.
Answer

Change in temperature has different effects on the solubility of different compounds. Usually the solubility increases with the increase in temperature, but it cannot be taken as a general rule.

  • Increases: potassium nitrate (KNO₃), silver nitrate (AgNO₃), potassium chloride (KCl), copper sulphate, sodium nitrate.
  • Does not increase appreciably: sodium chloride.
  • Decreases: lithium carbonate (Li₂CO₃), calcium chromate (CaCrO₄), calcium hydroxide, and gases.
SQ 1.54
Why are soda water bottles stored in the refrigerator?
Answer

Generally the solubility of gases decreases with increase in temperature. Carbon dioxide gas is more soluble in water at low temperature, so soda water bottles are stored in the refrigerator to keep carbon dioxide dissolved for a longer period of time.

SQ 1.55
What happens when a saturated solution of sugar is heated and more sugar is added?
Answer

By heating the solution, the quantity of sugar dissolved in water increases, i.e. the solubility of sugar increases with temperature, so the added sugar dissolves.

Part 4of 6

Constructed Response Questions

These test whether you really understand. Give a reason every time.

CRQ 1.1

How does a supercritical state look like?

Answer

Supercritical fluids are highly compressed states which show both properties of gases and liquids.

In a supercritical state there is no visible boundary between liquid and gas. Above its critical temperature and pressure (for CO₂, about 31 °C and 73 atm) the substance becomes one uniform fluid: as dense as a liquid but filling its container like a gas. The meniscus that separates a liquid from its vapour disappears.

CRQ 1.2

In what way is plasma created in a fluorescent tube?

Answer

Plasma is composed of particles with very high kinetic energy and can be considered as a partially ionised gas containing electrons, ions and photons. It exists in fluorescent tubes.

  1. The tube contains a gas (mercury vapour and argon) at low pressure.
  2. A high voltage across the electrodes accelerates electrons.
  3. They hit gas atoms and knock electrons out of them, so the gas becomes a mixture of ions and free electrons: plasma.
  4. The excited atoms give out ultraviolet light, which makes the coating on the tube glow.
CRQ 1.3

Most of the molecules we study in biochemistry are organic in nature. Where does the difference exist between the organic chemistry and biochemistry branches?

Answer

Organic chemistry deals with the carbon compounds (hydrocarbons and their derivatives): their structure, formation, properties, composition and reactions, whether or not they come from living things (plastics, fuels, dyes).

Biochemistry is the branch in which we understand life through chemical processes: the study of chemical substances and vital processes occurring in living organisms, such as the structure and function of proteins, carbohydrates, lipids and nucleic acids. The difference is biochemistry's focus on life processes.

CRQ 1.4

Give the reason for the brilliance shown by diamond. Can you improve it?

Answer

Diamond bends light very strongly (high refractive index, 2.42). Light entering a diamond is reflected again and again inside it by total internal reflection and comes out from the top, split into colours. That gives its sparkle.

Yes: the brilliance is improved by cutting and polishing the diamond into many precisely angled faces (facets), as in the "brilliant cut", so that more light is reflected back to the eye.

CRQ 1.5

Explain the dissolution of sodium chloride in water.

Answer

In a true solution the solute particles are completely homogenised in the solvent; dissolution of sodium chloride in water is the book's example.

  1. NaCl is made of Na⁺ and Cl⁻ ions in a crystal lattice.
  2. Water molecules are polar: the O end is partly negative, the H ends partly positive.
  3. The O ends of water molecules pull Na⁺ ions and the H ends pull Cl⁻ ions out of the crystal.
  4. Each ion is surrounded by water molecules (hydrated) and spreads through the water, forming a solution. At 20 °C, 36 g of NaCl dissolves in 100 g of water.
CRQ 1.6

Why do different compounds have different solubilities in water at a particular temperature?

Answer

Different solutes have different solubilities in a particular solvent. For example, 36 g of sodium chloride dissolves in 100 g of water at 20 °C, against 203.9 g of table sugar. This is because sugar molecules are larger than salt ions, so more water molecules can surround a single sugar molecule.

In general, solubility depends on the balance between the forces holding the solute together and the attraction between the solute particles and water molecules, which differ with the size, charge and polarity of the particles.

CRQ 1.7

Why can NaCl not be crystallised from water just like KNO₃?

Answer

The solubility of KNO₃ increases a lot with temperature (about 169 g per 100 g at 80 °C but 32 g at 20 °C), so cooling a hot saturated solution throws out a large amount of crystals.

The solubility of sodium chloride in water does not increase appreciably with the increase in temperature (about 36–39 g per 100 g), so cooling gives almost no crystals. NaCl is obtained by evaporating the water instead.

01020304050607080901001101201301401500102030405060708090100KINaNO₃KNO₃NH₄ClHClNH₃KClNaClKClO₃SO₂Temperature (°C)grams of solute per 100 g H₂Osolid lines: salts · dashed lines: gases
KNO₃ rises steeply; NaCl is almost flat.
CRQ 1.8

Why is graphite slippery to touch? Which property of graphite enables it to be used as a lubricant?

Answer

Graphite has a layered structure of hexagonal rings of carbon. The atoms inside a layer are strongly bonded, but the layers are not bonded strongly to each other, so they can slip past each other. This makes graphite slippery, and this property makes it a lubricant in industry (and makes pencils leave marks).

Part 5of 6

Comprehensive (Long) Questions

Long answers, explained in full with headings. Learn the structure: definition, explanation, diagram or table, example.

Only the long questions on one page →

Set A: Textbook comprehensive questions 8 questions

The long questions at the end of the chapter in your book.

Long Q 1.1

Mention the name of the branch of chemistry in which you will study each of the following topics: (a) rate of a reaction (b) digestion of food in the human body (c) properties of plasma (d) ecosystem (e) reactions taking place during fireworks (f) measurement of the absorption of wavelength with the help of an ultraviolet spectrometer.

Answer
TopicBranchReason (book)
(a) Rate of a reactionPhysical chemistryused to predict and change the rates of reactions
(b) Digestion of foodBiochemistryvital processes occurring in living organisms
(c) Properties of plasmaPhysical chemistryhow substances behave at atomic and molecular levels
(d) EcosystemEnvironmental chemistrychemical species in the air, soil and water
(e) FireworksInorganic chemistryreactions of metal salts, nitrates and sulphur
(f) UV spectrometerAnalytical chemistryanalysis with modern instruments
Long Q 1.2

What are allotropic forms? Explain the allotropic forms of carbon and sulphur. How does coal differ from diamond?

Answer

Allotropy

Elements may exist in more than one structural form which can exhibit quite different physical and chemical properties. These forms are called allotropic forms and the phenomenon is called allotropy. Element oxygen exists in two allotropic forms, namely oxygen (O₂) and ozone (O₃).

Allotropes of carbon

Carbon exists in three main allotropic forms: diamond, graphite and buckminster fullerene.

Diamondeach C bonded to 4 othersGraphitelayers of hexagonsBuckminster fullereneC₆₀ cage: 12 pentagons, 20 hexagonsweak forces between layers (dashed)
Diamond, graphite and fullerene.
  • Diamond has a giant macromolecular structure: every carbon atom is bonded to four others. It is the hardest substance, used in cutting and drilling tools, and does not conduct electricity.
  • Graphite has a layered structure of hexagonal rings of carbon. The layers slide over each other, so it is soft and slippery (lubricant, pencils); mobile electrons between the layers make it a conductor (electrodes).
  • Buckminster fullerene (C₆₀) consists of spheres made of atoms arranged in pentagons and hexagons. Fullerenes are stable at high temperatures and pressures and soluble in organic solvents. The molecule is not charged, has no boundaries and no unpaired electrons: a cage-like structure. C₆₀ has a low melting point, is soft and cannot conduct electricity.

Allotropes of sulphur

Element sulphur exists in two crystalline allotropic forms, rhombic and monoclinic; the former is more stable than the latter (monoclinic needles are stable only above about 96 °C).

Coal and diamond

CoalDiamond
Amorphous form of carbon (no regular arrangement)Crystalline form, regular 3-D network
Black, dull, soft, impureTransparent, brilliant, hardest
Used as a fuel in power stationsUsed in jewellery and cutting tools
Long Q 1.3

What are supercritical fluids? How are they different from ordinary liquids?

Answer

Definition

Matter also exists in intermediate states where liquid meets gas. Supercritical fluids are highly compressed states which show both properties of gases and liquids. A substance becomes supercritical when it is held above its critical temperature and critical pressure.

Example

Carbon dioxide above about 31 °C and 73 atm becomes supercritical CO₂.

Differences from ordinary liquids

Ordinary liquidSupercritical fluid
Has a surface (meniscus) separating it from its vapourNo boundary: one uniform phase
Has a fixed volumeExpands to fill its container like a gas
Flows slowly, spreads slowly into solidsVery low viscosity: penetrates solids like a gas
Dissolving power fixed by temperatureDissolving power changed by changing pressure

Importance

Chemical reactions which may not be carried out in conventional solvents may possibly be carried out in supercritical carbon dioxide. It is also used to remove caffeine from coffee and leaves no harmful solvent behind.

Long Q 1.4

Define solubility of a solute. How does the solubility of solutes change with the increase in temperature?

Answer

Definition

The solubility of a solute is the amount of solute which can dissolve in 100 g of a solvent at a particular temperature. Different solutes have different solubilities: at 20 °C, 36 g of NaCl but 203.9 g of table sugar dissolve in 100 g of water.

Solubility curves

01020304050607080901001101201301401500102030405060708090100KINaNO₃KNO₃NH₄ClHClNH₃KClNaClKClO₃SO₂Temperature (°C)grams of solute per 100 g H₂Osolid lines: salts · dashed lines: gases
Solubility against temperature.

Effect of temperature

Change in temperature has different effects on the solubility of different compounds. Usually the solubility increases with the increase in temperature but it cannot be taken as a general rule.

  • Increases: potassium nitrate (KNO₃), silver nitrate (AgNO₃), potassium chloride (KCl), copper sulphate and sodium nitrate.
  • Does not increase appreciably: sodium chloride.
  • Decreases: lithium carbonate (Li₂CO₃), calcium chromate (CaCrO₄) and calcium hydroxide.
  • Gases: the solubility of gases in water also decreases with the increase in temperature.

Activity

Take 100 g of water in a beaker and prepare a saturated solution of sugar at room temperature. Heat the beaker on a spirit lamp, add a little more sugar and stir: it dissolves. By heating, the quantity of sugar dissolved in water has increased, i.e. the solubility of sugar has increased.

Long Q 1.5

What types of movements are present in gaseous and liquid molecules?

Answer

Kinds of molecular motion

  • Translational: moving from one place to another.
  • Rotational: spinning about an axis.
  • Vibrational: moving to and fro about a position.

In gases

In gases, molecules are very widely apart with no order whatsoever and very weak intermolecular forces. They have all three motions: they move freely and randomly in straight lines between collisions (translational), spin (rotational) and vibrate. This is why gases spread and fill their containers.

In liquids

Liquids have molecules which are closely attached but moving randomly; significant intermolecular forces exist between them. They also have all three motions, but their translational motion is restricted: they slide over one another, which makes liquids flow.

In solids (for comparison)

The particles in solids remain fixed at their positions where they can only oscillate about their mean positions.

Solidfixed positions, vibrateLiquidclose, slide past each otherGasfar apart, move freelyheating: the molecules move faster and further apart
Particle motion in the three states.
Long Q 1.6

Differentiate between the areas which are studied under inorganic and organic chemistry.

Answer
Inorganic chemistryOrganic chemistry
Study of the synthesis, composition, properties and structure of elements and compounds that contain little or no carbonDeals with the carbon compounds (hydrocarbons and their derivatives)
Substances composed of metals, non-metals or their mixtures, salts, acids and basesStructure, formation, properties, composition and reactions of carbon-containing compounds
Includes simple carbon salts like carbonates, bicarbonates, oxides and carbidesExcludes those simple salts of carbon
Used as fertilisers, medicines, catalysts, pigments, coatingsFound in all forms of life and essential for life
Long Q 1.7

(Investigative) Preparation of solutions leads to an important process which enables us to purify a compound through crystallisation. Describe a process in which potassium nitrate is purified by crystallising it in water.

Answer

Principle

The increase in the solubility of solids in liquids with increase in temperature may be used to purify them. Pure solids commonly appear as beautifully shaped crystals. KNO₃ is far more soluble in hot water than in cold (about 169 g per 100 g at 80 °C but only about 32 g at 20 °C). Impurities, present in small amounts, stay dissolved when the solution cools.

Method

  1. Dissolve the impure KNO₃ in the minimum amount of hot water to make a hot saturated solution.
  2. Filter it while hot to remove insoluble impurities such as sand.
  3. Let the filtrate cool slowly; pure KNO₃ crystals form as its solubility falls.
  4. Filter off the crystals; the soluble impurities stay in the remaining solution.
  5. Wash the crystals with a little cold water and dry them between filter papers.
01020304050607080901001101201301401500102030405060708090100KINaNO₃KNO₃NH₄ClHClNH₃KClNaClKClO₃SO₂Temperature (°C)grams of solute per 100 g H₂Osolid lines: salts · dashed lines: gases
The steep KNO₃ curve is why cooling gives so many crystals.

Result

Worked exampleFrom 100 g of water
  1. At 80 °C about 169 g dissolves; at 20 °C only about 32 g stays dissolved.

Answerabout 137 g of pure KNO₃ crystallises out

Long Q 1.8

(Investigative) Graphene is called a miracle material and the material of the future. Which of its many properties makes it very useful in electronics?

Answer

Graphene is an example of a two-dimensional crystal, a single layer of carbon atoms arranged in a hexagonal pattern. It is a tough, flexible and light material with a high resistance.

  • Very high electrical conductivity: electrons move through it faster than through copper or silicon, so devices can be faster.
  • Only one atom thick and transparent: suitable for touch screens and see-through electrodes.
  • Flexible yet very strong: it can be used in bendable phones and wearable electronics.
  • Excellent conductor of heat: it carries heat away from chips, so they do not overheat.
  • Very large surface area: useful in sensors and fast-charging batteries.
Conclusion

Its outstanding electrical conductivity, combined with being thin, strong and flexible, is what makes graphene so promising in electronics.

Set B: More important long questions 5 questions

Long questions often set in board papers from this chapter, answered in the same full style.

Imp. LQ 1

What are elements, compounds and mixtures? Give the differences between them with examples.

Answer

Matter in this world exists in the form of elements, compounds and mixtures.

Element

Element is the simplest form of matter. It is a pure substance containing the same kind of atoms. It cannot be broken down into simpler substances by ordinary chemical reactions. Elements exist in all three forms, but most elements found in this world exist in solid form. Elements may be a metal, a non-metal, a metalloid or a noble gas, and can exist as atoms, molecules, ions and isotopes. Examples: sodium, potassium, carbon, nitrogen, oxygen, chlorine, copper, gold, mercury.

Compound

Compound is also a pure substance. It is made up of two or more different elements chemically combined in a fixed ratio. When elements come together they react and form chemical bonds that are not easy to break. Compounds may be molecular, ionic, intermetallic and coordination complexes, and inorganic or organic. Examples: water, ammonia, methane, carbon dioxide, sodium carbonate, potassium chloride, starch, proteins.

Mixture

A mixture is formed when more than one type of elements or compounds are mixed together in any ratio. Air, soil, milk and tap water are everyday examples. A mixture may be homogeneous (a solution of salt in water, uniform throughout) or heterogeneous (a sample of rock, whose composition differs from part to part).

Elementone kind of atomCompoundatoms bonded in a fixed ratioMixturesubstances mixed, not bonded
Particles in an element, a compound and a mixture.

Differences

ElementCompoundMixture
An element is the simplest form of matter. It is a pure substance containing the same kind of atoms.A compound is a pure substance formed by the chemical combination of two or more atoms of different elements.A mixture is an impure substance: more than one type of elements or compounds mixed in any ratio.
It is not possible to break down an element into simpler particles by ordinary chemical reactions.In a compound the atoms combine in a fixed ratio by weight; in water H : O = 1 : 8.Each component of a mixture retains its identity and specific properties.
When it exists as atoms it is represented by a symbol, e.g. Na and Ca.It can be broken into its elements by a chemical reaction, e.g. ammonia → nitrogen + hydrogen.It may be homogeneous (salt solution) or heterogeneous (rock).
Gaseous elements exist as independent molecules (N₂, O₂, Cl₂); noble gases are monatomic (He, Ar).Its properties are always different from those of its elements (water vs hydrogen and oxygen).Components are not chemically bound and can be separated by physical methods.
—Compounds exist as molecules (HCl, NH₃, H₂O) or as networks (NaCl, SiO₂).The properties of a mixture are the sum of those of its components.
Imp. LQ 2

Compare the properties of solids, liquids and gases. What is plasma?

Answer

States of matter

A state of matter is one of the many distinct forms in which matter can exist. The three primary states, solid, liquid and gas, are different from each other due to the different strength of intermolecular forces, the arrangement of particles and the distance between the particles.

Solidfixed positions, vibrateLiquidclose, slide past each otherGasfar apart, move freelyheating: the molecules move faster and further apart
Solid, liquid and gas.

Gases

In gases, molecules are very widely apart with no order and very weak intermolecular forces. This makes gases easily compressible, and their densities are very low.

Liquids

Liquids have molecules which are closely attached but moving randomly, with significant intermolecular forces. Liquids are therefore not easily compressible and their densities are higher than those of gases.

Solids

Solids have a definite shape and a fixed volume. Particles are closely packed with very strong attractions and remain fixed at their positions, oscillating about their mean positions. Solids are relatively incompressible and rigid, have very high densities and are the only state that does not need a container.

SolidLiquidGas
Arrangementclosely packed, fixedclose, randomfar apart, no order
Forcesvery strongsignificantvery weak
Densityvery highhigher than gasesvery low
Compressibilityalmost nonenot easilyeasily
Fluiditynoneflowsflows freely
Shape / volumefixed / fixednot fixed / fixednot fixed / not fixed

Plasma

Plasma is composed of particles with very high kinetic energy. It exists in fluorescent tubes, lightning and welding arcs. Plasma can be considered as a partially ionised gas containing electrons, ions, photons, etc. It is regarded as the fourth state of matter; most of the matter in the rest of the universe exists in this state.

Imp. LQ 3

Differentiate between a true solution, a colloidal solution and a suspension with examples.

Answer
SolutionColloidal solutionSuspensionparticles: cannot be seenparticles: cannot be seenparticles: can be seenon standing: do not settleon standing: do not settleon standing: settle downfilter paper: pass throughfilter paper: pass throughfilter paper: left as residue
Behaviour on standing and on filtering.

True solution

A solution is such a mixture in which solute particles are completely homogenised in the solvent, e.g. sodium chloride or copper sulphate in water. The particles cannot be seen by the naked eye, and on filtering they pass through the pores of filter paper leaving no residue.

Suspension

A suspension is a mixture in which solute particles do not dissolve in the solvent. We can see these particles. If kept for some time they settle down, and on filtering they cannot pass through the filter paper and are collected as a residue. Example: chalk in water.

Colloidal solution

In a colloidal solution the solute particles do not homogenise with the solvent. They are a little bigger than those of a true solution but not big enough to be seen with the naked eye. If kept for some time they do not settle down, and on filtration they pass through the filter paper. Examples: starch solution, white of an egg.

True solutionColloidSuspension
Particles visible?nonoyes
Settle on standing?nonoyes
Pass through filter paper?yesyesno (residue)
Examplesalt waterstarch, egg whitechalk in water
Imp. LQ 4

Explain saturated, unsaturated and supersaturated solutions with the help of a solubility curve.

Answer

Unsaturated solution

Take about 100 g of water in a beaker, add 5 g of table sugar and stir: it dissolves; another 5 g also dissolves. A solution which can dissolve more amount of a solute at a particular temperature is called an unsaturated solution.

Saturated solution

Continue adding sugar. A stage comes when no more sugar will dissolve at this temperature and any more settles at the bottom. A solution in which the maximum amount of the solute has been dissolved in a particular amount of a solvent at a particular temperature is called a saturated solution.

Supersaturated solution

Definition
Supersaturated solution

Holds more solute than a saturated solution at that temperature. It is unstable: a small crystal added makes the extra solute crystallise out. It is made by cooling a hot saturated solution slowly without disturbing it.

On a solubility curve

255075100125150175200225250020406080100ABCSupersaturatedC: 100 g at 40 °C (above the curve)UnsaturatedA: 30 g at 40 °C (below)Saturatedon the curve · B: 64 g at 40 °CTemperature (°C)g of KNO₃ per 100 g water
Points below, on and above the KNO₃ curve.
  • A point below the curve: unsaturated.
  • A point on the curve: saturated.
  • A point above the curve: supersaturated.
Worked exampleKNO₃ at 40 °C (solubility about 64 g per 100 g water)
  1. 30 g dissolved: unsaturated.
  2. 64 g dissolved: saturated.
  3. Cooled from 60 °C holding 100 g without crystallising: supersaturated.

Answerthe curve tells which kind a solution is

Imp. LQ 5

Describe the main branches of chemistry.

Answer

To understand the widely spread complex subject of chemistry and to concentrate on its specific aspects, chemistry is divided into many distinct branches.

  1. Physical chemistry investigates how substances behave at atomic and molecular levels; it is used to predict and change the rates of reactions and optimise industrial conditions.
  2. Inorganic chemistry is the study of the synthesis, composition, properties and structure of elements and compounds that contain little or no carbon; used as fertilisers, medicines, catalysts, pigments and coatings.
  3. Organic chemistry deals with carbon compounds (hydrocarbons and their derivatives) other than simple salts like carbonates, bicarbonates, oxides and carbides; organic compounds are essential for life.
  4. Environmental chemistry is the study of the chemical and biochemical phenomena in this planet: sources, reactions, effects and fates of chemicals in air, soil and water; causes and solutions of pollution.
  5. Analytical chemistry deals with the analysis of substances: separation, identification and determination of concentration, with modern instruments.
  6. Biochemistry is the branch in which we understand life through chemical processes: proteins, carbohydrates, lipids and nucleic acids.
  7. Nuclear chemistry deals with reactions in the nucleus of an atom: radioactivity; applications in agriculture, medicine, industry and research.
  8. Polymer chemistry focuses on the properties, structure and synthesis of polymers, large molecules made by linking building blocks (proteins, cellulose, nucleic acids).
  9. Geochemistry is the study of the chemical composition of the Earth and its minerals; mineral exploration, environmental monitoring, forestry, medical research.
  10. Medicinal chemistry: the chemist designs and synthesises medicines; discovery, delivery, absorption and metabolism of drugs.
  11. Astrochemistry is the study of molecules and ions in space and interstellar space and their interaction with radiation.
Part 6of 6

Revision, Practice and Self-Test

Use this the night before the test.

One-page key facts

Chemistry
Composition, structure, properties and changes of matter
Matter
Has mass and occupies space
Density order
solid > liquid > gas
Compressibility order
gas > liquid > solid
Plasma
Partially ionised gas: neon signs, lightning, Sun
Liquid crystal
Between liquid and crystalline solid: LCDs
Supercritical fluid
Between liquid and gas: supercritical CO₂
Allotropes of carbon
Diamond, graphite, fullerene C₆₀
Allotropes of sulphur
Rhombic, monoclinic
Water by mass
H : O = 1 : 8
Solubility
g of solute per 100 g solvent at a given temperature
At 20 °C
NaCl 36 g, sugar 204 g per 100 g water

Key definitions 15 terms

Chemistry
Chemistry is the branch of science which deals with the properties, composition and the structure of substances. It also deals with the physical and chemical changes in matter and the laws or principles which govern these changes.
Matter
Anything other than energy which carries weight and occupies volume is called matter. Energy is non-material in nature.
State of matter
A state of matter is one of the many distinct forms in which matter can exist. We observe four states in everyday life: solid, liquid, gas and plasma.
Plasma
Plasma is composed of particles with very high kinetic energy. It can be considered as a partially ionised gas containing electrons, ions, photons, etc. It exists in fluorescent tubes, lightning and welding arcs.
Exotic states
States of matter that are not commonly encountered are called exotic states of matter, e.g. dark matter, Bose-Einstein condensate, nuclear matter and quantum spin liquid.
Element
Element is the simplest form of matter. It is a pure substance containing the same kind of atoms. It cannot be broken down into simpler substances by ordinary chemical reactions.
Compound
Compound is also a pure substance. It is made up of two or more different elements chemically combined in a fixed ratio. Examples: water, ammonia, methane, carbon dioxide.
Mixture
A mixture is formed when more than one type of elements or compounds are mixed together in any ratio. Examples: air, soil, milk, tap water.
Allotropy
Elements may exist in more than one structural form which can exhibit quite different physical and chemical properties. These forms are called allotropic forms and the phenomenon is called allotropy.
True solution
A solution is such a mixture in which solute particles are completely homogenised in the solvent, e.g. sodium chloride or copper sulphate in water. The particles cannot be seen and pass through filter paper leaving no residue.
Colloidal solution
A mixture whose solute particles are a little bigger than those of a true solution but not big enough to be seen with the naked eye. They do not settle down and pass through filter paper. Examples: starch solution, white of an egg.
Suspension
A suspension is a mixture in which solute particles do not dissolve in the solvent. The particles can be seen, settle down on standing and are collected as a residue on filter paper. Example: chalk in water.
Unsaturated solution
A solution which can dissolve more amount of a solute at a particular temperature is called an unsaturated solution.
Saturated solution
A solution in which the maximum amount of the solute has been dissolved in a particular amount of a solvent at a particular temperature is called a saturated solution.
Solubility
The solubility of a solute is the amount of solute which can dissolve in 100 g of a solvent at a particular temperature.

Common mistakes to avoid

  • Calling milk a suspension: it is a colloid.
  • Saying colloid particles are left on filter paper: only suspension particles are.
  • Saying solubility always rises with temperature: gases and a few solids are exceptions.
  • Mixing up graphite (many layers) and graphene (one layer).
  • Saying "water has H and O in 2 : 1 by mass": that is by atoms; by mass it is 1 : 8.
  • Confusing allotropes (same element, different structure) with isotopes.
  • Putting the rate of any reaction in organic chemistry: rates are physical chemistry.
  • Calling a mixture a compound because it is uniform: a solution is a homogeneous mixture.

Extra practice tap a question to see its answer

  1. Name the state of matter in a welding arc.Show answer

    Plasma

  2. Which branch studies molecules in interstellar space?Show answer

    Astrochemistry

  3. Give two natural polymers.Show answer

    Starch, cellulose (or protein)

  4. Why are gases easily compressed?Show answer

    Their particles are very far apart

  5. Name one use of liquid crystals.Show answer

    Display screens of watches and monitors

  6. Name two allotropes of oxygen.Show answer

    O₂ and O₃ (ozone)

  7. Why is diamond hard?Show answer

    Each C is bonded to four others in a rigid 3-D network

  8. Is tap water an element, compound or mixture?Show answer

    A mixture

  9. Starch solution: true solution, colloid or suspension?Show answer

    Colloid

  10. What happens to the solubility of CO₂ in water on heating?Show answer

    It decreases

  11. 30 g of NaCl is dissolved in 100 g water at 20 °C. Saturated?Show answer

    No, unsaturated (36 g needed)

  12. How is pure NaCl obtained from its solution?Show answer

    By evaporation (its solubility hardly changes with temperature)

  13. Name the first artificially made element.Show answer

    Technetium

  14. What is the more stable allotrope of sulphur?Show answer

    Rhombic sulphur

Final self-test

Final self-test: all 24 MCQs, no answers

Give yourself 25 minutes. Pick one option for each question, then submit to see your score and which questions to revise. Any question you get wrong tells you which topic to read again.

End of Part 6Back to Part 1 ↑
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Periodic Table and Periodicity
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Group Properties and Elements
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Hydrocarbons
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Empirical Data Collection and Analysis
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13Chapter
Laboratory and Practical Skills
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