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MDCAT Chemistry — Atomic Structure

Atomic Structure is a core Chemistry topic in the PMDC MDCAT syllabus, covering 9 subtopics. Below are the subtopics to revise, how often the topic appears in past papers, and real past-paper MCQs to try.

Subtopics (9)

  • Discovery of Electron (Cathode Rays)
  • Discovery of Proton
  • Electronic Configuration
  • Ionization Energy of Hydrogen (Bohr Model)
  • Mass Spectrometry
  • Planck's Quantum Theory
  • Quantum Numbers
  • Shapes of Orbitals
  • Spectrum of Hydrogen

How Atomic Structure is tested

Across the 16 MDCAT past papers on ParhaiKrlo, Atomic Structure accounts for 50 questions. It appears in all 16, about 3.1 questions a paper. The heaviest was MDCAT 2024, with 5 questions, and the most recent is MDCAT 2025, with 4.

Atomic Structure questions per paper
PaperQuestions
MDCAT 20254
MDCAT 20245
MDCAT 20235
MDCAT 20221
MDCAT 20192
MDCAT 20181
MDCAT 20175
MDCAT 20162
MDCAT 20154
MDCAT 20142
MDCAT 20132
MDCAT 20122
MDCAT 20113
MDCAT 20105
MDCAT 20095
MDCAT 20082

Atomic Structure MCQs from the MDCAT past papers

Try each one before opening the answer. Each comes with a short explanation.

  1. Q1 · MDCAT 2025 · Atomic Structure

    Which set of quantum numbers is not allowed for an electron?

    • A.n=2, l=1, m=0, s=+1/2
    • B.n=3, l=0, m=0, s=-1/2
    • C.n=2, l=2, m=1, s=+1/2
    • D.n=1, l=0, m=0, s=+1/2
    Show answer

    Answer: C. n=2, l=2, m=1, s=+1/2 — n=2, l=2, m=1, s=+1/2 is not allowed because l cannot equal or exceed n.

  2. Q2 · MDCAT 2024 · Atomic Structure

    The type and relative amount of each isotope in an element can be found by:

    • A.R spectroscopy
    • B.U. V spectroscopy
    • C.Mass Spectrometry
    • D.N.M.R
    Show answer

    Answer: C. Mass Spectrometry — Mass spectrometry identifies isotopes and measures their relative abundance.

  3. Q3 · MDCAT 2023 · Atomic Structure

    When 6d orbital is filled, the entering electron goes into:

    • A.7f
    • B.7d
    • C.7p
    • D.7s
    Show answer

    Answer: C. 7p — After the 6d orbital fills, the next electron enters the 7p orbital, following the standard Aufbau filling order.

Practice this topic

Practice Atomic Structure MCQs ›Full Chemistry syllabus ›

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